Study on Removal of Heavy Metal from Water by Oxidized Agricultural Byproducts
Main Article Content
Abstract
In this article, hydrogen peroxide was used to modify jute and coir. IR spectrum of the materials showed the appearance of carboxyl groups on oxidized materials which enhances ion adsorption capacity for metals. Modified jute and coir was choiced to study the influential parameters such as initial metal ion concentration, contact time and pH of the solution on the adsorption process. The experimental data was well fitted by the pseudo-second-order kinetics model and Langmuir isotherm model. This study showed that under optimum conditions (pH = 5 and contact time of Ni and Pb experiment chosen at 30 and 120 minutes, repectively), modified coir had the highest potential of removal for metal ions, with maximum adsorption capacities were 48.54 mg/g and 19.34 mg/g for Pb(II) and Ni(II), respectively.
Keywords:
Heavy metal, agricultural by-product, adsorption material
References
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[5] Laszlo J. A., Dintzis F. R. (1994), “Crop Residues as Ion-Exchange Materials. Treatment of Soybean Hull and Sugar Beet Fiber (Pulp) with Epichlorohydrinto Improve Cation-Exchange Capacity and Physical Stability”, Journal of Applied Polymer Science, Vol. 52,531-538.
[6] Mohanty A.K., Misra M., Drzal L.T. (2001), “Surface modifications of natural fibers and performance of the resulting biocomposites: An overview”, Compos Interfaces 8:313, pp313-343
[7] Rowell R.M., Young R.A., Rowell J.K. (1997) “Paper and composites from agro-based resources”. CRC Lewis Publishers, Boca Raton FL.
[8] Inyang M., Gao B., Yao Y., Xue Y., Zimmerman A.R., Pullammanappallil P., Cao X. (2012), “Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass”, Bioresource Technology, 110; 50–56
[9] Kılıc M., Kırbıyık C., Cepeliogullar Ö., Pütün A.E. (2013), “Adsorption of heavy metal ions from aqueous solutions by bio-char, a by-product of pyrolysis”, Applied Surface Science, 283; 856–862.
[10] Pellera F.M., Giannis A., Kalderis D., Anastasiadou K., Stegmann R., Wang J.Y, Gidarakos E. (2012), “Adsorption of Cu(II) ions from aqueous solutions on biochars prepared from agricultural by-products”, Journal of Environmental Management,96; 35-42.
[11] Krowiak A.W., Szafran R.G., Modelski S. (2011), “Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent”, Desalination, 265; 126–134.
[12] Feng N, Guoa Y., Lianga S., Zhub Y., Liu J. (2011), “Biosorption of heavy metals from aqueous solutions by chemically modified orange peel”, Journal of Hazardous Materials, 185; 49–54.
[13] Nada A.a.a., Eid M.a., Bahnasawy R.R.RL, Khalifa M.n. (2002), “Preparation and Characterization of Cation Exchangersfrom Agricultural Residues”, Journal of Applied Polymer Science, 85, 792–800.
[14] Fourest E., Volesky B. (1995), “Contribution of Sulfonate Groups and Alginate to Heavy Metal Biosorption by the Dry Biomass of Sargassum fluitans”, Environ. Sci. Technol. 30 (1), pp 277–282
[15] Anirudhan T.S., Senan P., Unnithan M.R. (2007), “Sorptive potential of a cationic exchange resin of carboxyl banana stem for mercury(II) from aqueous solutions”, Separation and Purification Technology, 52,; pp. 512–519
[16] A. M. A. Nada, M. D. Badry & K. N. Abd EI-Nour (1992), “Grafting of cellulose and carboxymethylated cellulose with methyl methacrylate and the dielectric properties of the products”, Polymer Degradation and Stability, 36,; pp.201-205.
[17] Ney, P. (1982) Melliand Textilber. 63, 443-450.
[18] Eiichi M., Tetsuo K. (1984), “Properties of 2,3-Dicarboxy Cellulose Combined with Various Metallic Ions”, Journal of Applied Polymer Science, 29, pp. 2289-2297
[19] Parovuori P., Hamunen A., Forssell P., Autio K., and Poutanen K. (1995), “Oxidation of Potato Starch by Hydrogen Peroxide”, Starch vol. 47 Nr. 1. S, pp. 19-23.
[20] Shukla S.R., Roshan S. P., Amit D. S. (2006), “Adsorption of Ni(II), Zn(II) and Fe(II) on modified coir fibres”, Separation and Purification Technology, 47;pp., 141–147.
[21] S. Lagergren, K. Sven (1989), “Zur theorie der sogenannten adsorption gelöster stoffe”, Vetenskapsakad, 24 ; pp., 1–39.
[22] McKay G., Ho Y.S., Ng J.C.Y. (1999) “Biosorption of copper from waste waters: a review”. Sep Purif Methods, 28; pp., 87–125.
[23] Ho Y.S., McKay G. (1999), “Pseudo-second order model for sorption processes”. Process Biochem. 34; pp., 451–465
[24] I. Langmuir (1916), “Constitution and fundamental properties of solids and liquids”, J. Am. Chem. Soc. 38; pp. 2221–2295.
[25] H.M.F. Freundlich (1906), “Uber die adsorption in losungen”, Z. Phys. Chem.,57 (A); pp. 385–470
[26] Leonard Y. Mwaikambo, Martin P. Ansell (2002), “Chemical Modification of Hemp, Sisal, Jute, and Kapok Fibers by Alkalization”, Journal of Applied Polymer Science, 84, pp. 2222–2234