Study on Adsorption of Methylene Blue from Aqueous Solution by Biochar Derived from Mimosa Pigra Plant
Main Article Content
Abstract
Biochar from mimosa pigra was studied to remove methylene blue (MB) from aqueous solution. The properties of biochars were determined using Fourier Transform Infrared, scanning electron microscope, and Brunauer–Emmett–Teller. The biochar achieved the yield of 24.62 % at 500 oC pyrolysis. The specific surface area of the biochar is 285.53 m2/g, the total pore size is 0.153 cm3/g and the ash content is 2.79%. The optimal dose of removing MB of the biochar is 5 g/L and the optimal pH is 2 - 10. MB removal reached over 80% in the first 30 min, followed by a stable period of 120 to 360 min reaching over 90% of removal. Maximum adsorption capacity reached 20.18 mg/g at 25 oC. MB adsorption data is suitable for kinetic models in order: Avrami > Elovich > PSO > PFO. The adsorption process may comprise physical and chemical adsorption andmultiple stages.
Keywords:
Biochar, methylene blue, dye, mimosa pigra, adsorption.
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[13] J. Zhang, M. Liu, T. Yang, K. Yang, H. Wang,
A Novel Magnetic Biochar from Sewage Sludge: Synthesis and Its Application for the Removal of Malachite Green from Wastewater, Water Science and Technology, Vol. 74, 2016, https://doi.org/10.2166/wst.2016.386.
[14] J. H. Park, J. J. Wang, Y. Meng, Z. Wei,
R. D. DeLaune, D. C. Seo, Adsorption/Desorption Behavior of Cationic and Anionic Dyes by Biochars Prepared at Normal and High Pyrolysis Temperatures, Colloids and Surfaces A: Physicochemical and Engineering Aspects,
Vol. 572, 2019, pp. 274-282, https://doi.org/10.1016/j.colsurfa.2019.04.029.
[15] N. Chaukura, E. C. Murimba, W. Gwenzi, Sorptive Removal of Methylene Blue from Simulated Wastewater Using Biochars Derived from Pulp and Paper Sludge, Environmental Technology & Innovation, Vol. 8, 2017, pp. 132-140, https://doi.org/10.1016/j.eti.2017.06.004.
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pp. 1423-1436, https://doi.org/10.1016/S0008-6223(99)00261-4.
[18] B. Ji, J. Wang, H. Song, W. Chen, Removal of Methylene Blue from Aqueous Solutions Using Biochar Derived from a Fallen Leaf by Slow Pyrolysis: Behavior and Mechanism, Journal of Environmental Chemical Engineering, Vol. 7,
No. 3, 2019, pp. 103036, https://doi.org/10.1016/j.jece.2019.103036.
[19] Y. Wang, R. Liu, Comparison of Characteristics of Twenty-One Types of Biochar and Their Ability to Remove Multi-Heavy Metals and Methylene Blue in Solution, Fuel Processing Technology, Vol. 160, 2017, pp. 55-63, https://doi.org/10.1016/j.fuproc.2017.02.019.
[20] W. Huang, J. Chen, J. Zhang, Adsorption Characteristics of Methylene Blue by Biochar Prepared Using Sheep, Rabbit and Pig Manure, Environmental Science and Pollution Research, Vol. 25, No. 29, 2018, pp. 29256-29266, https://doi.org10.1007/s11356-018-2906-1.
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T. D. Nguyen, Q. V. Ly, H. H. Ngo, D. V. N. Vo, T. P. Nguyen, I. T. Kim, Q. Van Le, Converting Biomass of Agrowastes and Invasive Plant into Alternative Materials for Water Remediation, Biomass Conversion and Biorefinery, 2021, https://doi.org/10.1007/s13399-021-01526-6.
[22] S. Lagergren, Zur Theorie Der Sogenannten Adsorption Gelöster Stoffe, Kungliga Svenska Vetenskapsakademiens, Handlingar, Vol. 24, 1898, pp. 1-39, https://doi.org/10.1007/BF01501332.
[23] Y. S. Ho, Second-Order Kinetic Model for the Sorption of Cadmium onto Tree Fern: A Comparison of Linear and Non-Linear Methods, Water Research, Vol. 40, No. 1, 2006, pp. 119-125, https://doi.org/10.1016/j.watres.2005.10.040.
[24] N. A. Oladoja, A Critical Review of the Applicability of Avrami Fractional Kinetic Equation in Adsorption-Based Water Treatment Studies, Desalination and Water Treatment,
Vol. 57, No. 34, 2016, pp. 15813-15825, https://doi.org/10.1080/19443994.2015.1076355.
[25] A. R. Cestari, E. F. S. Vieira, E. C. N. Lopes,
R. G. da Silva, Kinetics and Equilibrium Parameters of Hg(Ii) Adsorption on Silica–Dithizone, Journal of Colloid and Interface Science, Vol. 272, No. 2, 2004, pp. 271-276, https://doi.org/10.1016/j.jcis.2003.09.019.
[26] V. K. Gupta, B. Gupta, A. Rastogi, S. Agarwal,
A. Nayak, Pesticides Removal from Waste Water by Activated Carbon Prepared from Waste Rubber Tire, Water Research, Vol. 45, No. 13, 2011,
pp. 4047-4055, https://doi.org/10.1016/j.watres.2011.05.016.
[27] I. Langmuir, The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum, Journal of the American Chemical Society, Vol. 40, No. 9, 1918, pp. 1361-1403, https://doi.org/10.1021/ja02242a004.
[28] H. Freundlich, Über Die Adsorption in Lösungen, De Gruyter, Berlin, 1907.
[29] A. Demirbas, Effects of Temperature and Particle Size on Bio-Char Yield from Pyrolysis of Agricultural Residues, Journal of Analytical and Applied Pyrolysis, Vol. 72, No. 2, 2004,
pp. 243-248, https://doi.org/10.1016/j.jaap.2004.07.003.
[30] D. A. G. Sumalinog, S. C. Capareda, M. D. G. de Luna, Evaluation of the Effectiveness and Mechanisms of Acetaminophen and Methylene Blue Dye Adsorption on Activated Biochar Derived from Municipal Solid Wastes, The Journal of Environmental Management, Vol. 210, 2018, pp. 255-262, https://doi.org10.1016/j.jenvman.2018.01.010.
[31] A. A. Inyinbor, F. A. Adekola, G. A. Olatunji, Kinetics, Isotherms and Thermodynamic Modeling of Liquid Phase Adsorption of Rhodamine B Dye onto Raphia Hookerie Fruit Epicarp, Water Resources and Industry, Vol. 15, 2016, pp. 14-27, https://doi.org/10.1016/j.wri.2016.06.001.
[32] A. W. Samsuri, F. S. Zadeh, B. J. S. Bardan, Adsorption of as(Iii) and as(V) by Fe Coated Biochars and Biochars Produced from Empty Fruit Bunch and Rice Husk, Journal of Environmental Chemical Engineering, Vol. 1, No. 4, 2013,
pp. 981-988,
https://doi.org/10.1016/j.jece.2013.08.009.
[33] D. Kołodyńska, J. Bąk, Use of Three Types of Magnetic Biochar in the Removal of Copper(Ii) Ions from Wastewaters, Separation Science and Technology, Vol. 53, No. 7, 2018, pp. 1045-1057, https://doi.org10.1080/01496395.2017.1345944.
[34] T. M. A. Fattah, M. E. Mahmoud, S. B. Ahmed,
M. D. Huff, J. W. Lee, and S. Kumar, Biochar from Woody Biomass for Removing Metal Contaminants and Carbon Sequestration, Journal of Industrial and Engineering Chemistry, Vol. 22, 2015, pp. 103-109, https://doi.org/10.1016/j.jiec.2014.06.030.
[35] L. Sun, S. Wan, W. Luo, Biochars Prepared from Anaerobic Digestion Residue, Palm Bark, and Eucalyptus for Adsorption of Cationic Methylene Blue Dye: Characterization, Equilibrium, and Kinetic Studies, Bioresource Technology,
Vol. 140, 2013, pp. 406-413, https://doi.org/10.1016/j.biortech.2013.04.116.
[36] Y. S. Ho, C. C. Chiang, Y. C. Hsu, Sorption Kinetics for Dye Removal from Aqueous Solution Using Activated Clay, Separation Science and Technology, Vol. 36, No. 11, 2001, pp. 2473-2488, https://doi.org/10.1081/SS-100106104.
[37] A. Usman, M. Ahmad, M. E. Mahrouky,
A. Alomran, Y. S. Ok, A. Sallam, A. E. Naggar,
M. A. Wabel, Chemically Modified Biochar Produced from Conocarpus Waste Increases Removal from Aqueous Solutions, Environmental geochemistry and health, Vol. 38, No. 3, 2015,
pp. 511-521, https://doi.org/10.1007/s10653-015-9736-6.
[38] Z. AksuA. İ. Tatlı, Ö. Tunç, A Comparative Adsorption/Biosorption Study of Acid Blue 161: Effect of Temperature on Equilibrium and Kinetic Parameters, Chemical Engineering Journal,
Vol. 142, No. 1, 2008, pp. 23-39, https://doi.org/10.1016/j.cej.2007.11.005.
[39] B. Royer, N. F. Cardoso, E. C. Lima, T. R. Macedo, C. Airoldi, Sodic and Acidic Crystalline Lamellar Magadiite Adsorbents for the Removal of Methylene Blue from Aqueous Solutions: Kinetic and Equilibrium Studies, Separation Science and Technology, Vol. 45, No. 1, 2009, pp. 129-141, https://doi.org10.1080/01496390903256257.
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