Study on Adsorption of Nickel and Methylene Blue in Aqueous Solution by Magnetic Carboxylate-Rich Carbon
Main Article Content
Abstract
In this study, magnetic carboxylate-rich carbon material (Fe3O4@CRC) was synthesized via a low-temperature carbonization method and applied as an adsorbent for adsorption of Ni(II) ions and methylene blue (MB) in aqueous solution. The synthesized Fe3O4@CRC was characterized by various techniques (XRD, FTIR, FE-SEM, TEM, EDX, VSM, and BET). The adsorption kinetics, isotherms, thermodynamics, and the effects of key adsorption factors, including the pH value, initial adsorbate concentration, contact time, adsorbent dose and temperature were investigated in detail. The results showed that Fe3O4@CRC exhibited a high adsorption capacity for MB and Ni(II) with the maximum adsorption capacity of 187.26 mg/g and 106.75 mg/g, respectively. The adsorption of MB and Ni(II) on Fe3O4@CRC was a spontaneous and endothermic process, and was best described with the first-order kinetic model, Freundlich (for MB) and Langmuir (for Ni(II)) isotherm models. In addition, Fe3O4@CRC could maintain a high adsorption capacity after many consecutive cycles. Therefore, the Fe3O4@CRC material can be used as a highly efficient adsorbent for the removal of heavy metals and dyes from wastewater due to the advantages of high adsorption performance, easy separation, and good reusability.
Keywords:
Carboxylate-rich carbon, adsorption, nickel, methylene blue, magn.
References
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W. Li, Efficient Removal of Heavy Metal Ions and Organic Dyes with Cucurbit [8] Uril-Functionalized Chitosan, Journal of Colloid and Interface Science, Vol. 539, 2019, pp. 400-413. https://doi.org/10.1016/j.jcis.2018.12.078.
[2] H. Cangul, L. Broday, K. Salnikow, J. Sutherland, W. Peng, Q. Zhang, V. Poltaratsky, H. Yee,
M.A. Zoroddu, M. Costa, Molecular Mechanisms of Nickel Carcinogenesis, Toxicology Letters,
Vol. 127, No. 1-3, 2002, pp. 69-75. https://doi.org/10.1016/S0378-4274(01)00485-4.
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H. T. Nguyen, Utilization of Waste Plastic Pet Bottles to Prepare Copper-1,4-Benzenedicarboxylate Metal-Organic Framework for Methylene Blue Removal, Separation Science and Technology, Vol. 55, No. 3, 2020, pp. 444-455, https://doi.org/10.1080/01496395.2019.1577266.
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[7] J. Shu, S. Cheng, H. Xia, L. Zhang, J. Peng, C. Li, S. Zhang, Copper Loaded on Activated Carbon as an Efficient Adsorbent for Removal of Methylene Blue, RSC Advances, Vol. 7, No. 24, 2017,
pp. 1439-14405, https://doi.org/10.1039/C7RA00287D.
[8] Z. Ioannou, C. Karasavvidis, A. Dimirkou,
V. Antoniadis, Adsorption of Methylene Blue and Methyl Red Dyes from Aqueous Solutions onto Modified Zeolites, Water Science and Technology, Vol. 67, No. 5, 2013, pp. 1129-1136, https://doi.org/10.2166/wst.2013.672.
[9] E. Zanin, J. Scapinello, M. de Oliveira,
C. L. Rambo, F. Franscescon, L. Freitas, J. M. M. de Mello, M. A. Fiori, J. V. Oliveira, J. Dal Magro, Adsorption of Heavy Metals from Wastewater Graphic Industry using Clinoptilolite Zeolite as Adsorbent, Process Safety and Environmental Protection, Vol. 105, 2017, pp. 194-200, https://doi.org/10.1016/j.psep.2016.11.008.
[10] F. Y. Wang, H. Wang, J. W. Ma, Adsorption of Cadmium(II) Ions from Aqueous Solution by a New Low-Cost Adsorbent—Bamboo Charcoal, Journal of Hazardous Materials, Vol. 177, No. 1-3, 2010, pp. 300-306, https://doi.org/10.1016/j.jhazmat.2009.12.032.
[11] W. S. W. Ngah, L. C. Teong, M. A. K. M. Hanafiah, Adsorption of Dyes and Heavy Metal Ions by Chitosan Composites: A Review, Carbohydrate Polymers, Vol. 83, No. 4, 2011, pp. 1446-1456, https://doi.org/10.1016/j.carbpol.2010.11.004.
[12] Y. Feng, J. L. Gong, G. M. Zeng, Q. Y. Niu,
H. Y. Zhang, C. G. Niu, J. H. Deng, M. Yan, Adsorption of Cd (II) and Zn (II) from Aqueous Solutions using Magnetic Hydroxyapatite Nanoparticles as Adsorbents, Chemical Engineering Journal, Vol. 162, No. 2, 2010,
pp. 487-494, https://doi.org/10.1016/j.cej.2010.05.049.
[13] F. Perreault, A. Fonseca de Faria, M. Elimelech, Environmental Applications of Graphene-Based Nanomaterials, Chemical Society Reviews,
Vol. 44, No. 16, 2015, pp. 5861-5896, https://doi.org/10.1039/C5CS00021A.
[14] E. Santoso, R. Ediati, Y. Kusumawati, H. Bahruji, D.O. Sulistiono, D. Prasetyoko, Review on Recent Advances of Carbon Based Adsorbent for Methylene Blue Removal from Waste Water, Materials Today Chemistry, Vol. 16, 2020,
pp. 100233, https://doi.org/10.1016/j.mtchem.2019.100233.
[15] L. Qu, D. Huang, H. Shi, M. Gu, J. Li, F. Dong,
Z. Luo, TiO2/Carboxylate-rich Porous Carbon: A Highly Efficient Visible-Light-Driven Photocatalyst Based on the Ligand-to-Metal Charge Transfer (LMCT) Process, Journal of Physics and Chemistry of Solids, Vol. 85, 2015, pp. 173-179, https://doi.org/10.1016/j.jpcs.2015.05.016.
[16] Q. Wu, W. Li, S. Liu, Carboxyl-rich Carbon Microspheres Prepared from Pentosan with High Adsorption Capacity for Heavy Metal Ions, Materials Research Bulletin, Vol. 60, 2014,
pp. 516-523, https://doi.org/10.1016/j.materresbull.2014.09.01.
[17] T. T. N. Le, V. T. Le, M. U. Dao, Q. V. Nguyen, T. T. Vu, M. H. Nguyen, D. L. Tran, H. S. Le, Preparation of Magnetic Graphene Oxide/Chitosan Composite Beads for Effective Removal of Heavy Metals and Dyes from Aqueous Solutions, Chemical Engineering Communications, Vol. 206, No. 10, 2019, pp. 1337-1352, https://doi.org/10.1080/00986445.2018.1558215.
[18] F. Cheng, Characterization of Aqueous Dispersions of Fe3O4 Nanoparticles and their Biomedical Applications, Biomaterials, Vol. 26, No. 7, 2005, pp. 729-738, https://doi.org/10.1016/j.biomaterials.2004.03.01.
[19] S. Mahdavi, M. Jalali, A. Afkhami, Removal of Heavy Metals from Aqueous Solutions using Fe3O4, ZnO, and CuO Nanoparticles, in: Nanotechnology for Sustainable Development First Ed., 2014, https://doi.org/10.1007/978-3-319-05041-614.
[20] G. R. Chaudhary, P. Saharan, A. Kumar,
S. K. Mehta, S. Mor, A. Umar, Adsorption Studies of Cationic, Anionic and Azo-Dyes via Monodispersed Fe3O4 Nanoparticles, Journal of Nanoscience and Nanotechnology, Vol. 13, No. 5, 2013, pp 3240-3245, https://doi.org/10.1166/jnn.2013.7152.
[21] L. Qu, J. Jia, H. Shi, Z. Luo, One-step Synthesis of Fe3O4/Carboxylate-rich Carbon Composite and its Application for Cu(II) Removal, New Journal of Chemistry, Vol. 40, No. 3, 2016, pp. 2895-2903, https://doi.org/10.1039/c5nj02545a.
[22] L. Qu, Z. Luo, C. Tang, One Step Synthesis of Bi@Bi2O3@Carboxylate-rich Carbon Spheres with Enhanced Photocatalytic Performance, Materials Research Bulletin, Vol. 48, No. 11, 2013,
pp. 4601-4605, https://doi.org/10.1016/j.materresbull.2013.07.04.
[23] V. T. Le, T. K. N. Tran, D. L. Tran, H. S. Le,
V. D. Doan, Q. D. Bui, H. T. Nguyen, One-pot Synthesis of a Novel Magnetic Activated Carbon/Clay Composite for Removal of Heavy Metals from Aqueous Solution, Journal of Dispersion Science and Technology, Vol. 40, No. 12, 2019,
pp. 1761-1776, https://doi.org/10.1080/01932691.2018.1541414.
[24] X. Zhang, A. Lu, D. Li, L. Shi, Z. Luo, C. Peng, Simultaneous Removal of Methylene Blue and Pb2+ from Aqueous Solution by Adsorption on Facile Modified Lignosulfonate, Environmental Technology (United Kingdom), Vol. 41, No. 13, 2018, pp 1677-1690, https://doi.org/10.1080/09593330.2018.1544666.
[25] M. J. Livani, M. Ghorbani, Fabrication of NiFe2O4 Magnetic Nanoparticles Loaded on Activated Carbon as Novel Nanoadsorbent for Direct Red 31 and Direct Blue 78 Adsorption, Environmental Technology (United Kingdom). Vol. 39, No. 23, 2018, pp. 2977-2993, https://doi.org/10.1080/09593330.2017.1370024.
[26] N. Baig, Ihsanullah, M. Sajid, T. A. Saleh, Graphene-based Adsorbents for the Removal of Toxic Organic Pollutants: A Review, Journal of Environmental Management, Vol. 244, 2019,
pp. 370-382, https://doi.org/10.1016/j.jenvman.2019.05.047.
[27] A. Kuroki, M. Hiroto, Y. Urushihara, T. Horikawa, K. I. Sotowa, J. R. Alcántara Avila, Adsorption Mechanism of Metal Ions on Activated Carbon, Adsorption, Vol. 25, No. 9, 2019, pp. 1251-1258, https://doi.org/10.1007/s10450-019-00069-7.
[28] M. Jiang, X. Jin, X.-Q. Lu, Z. Chen, Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto Natural Kaolinite Clay, Desalination, Vol. 252, No. 1-3, 2010, pp. 33-39. https://doi.org/10.1016/j.desal.2009.11.005.
[29] N. S. Yousef, R. Farouq, R. Hazzaa, Adsorption Kinetics And Isotherms for the Removal of Nickel Ions from Aqueous Solutions by an Ion-Exchange Resin: Application of Two and Three Parameter Isotherm Models, Desalination and Water Treatment, Vol. 57, No. 46, 2016, pp. 21925-21938, https://doi.org/10.1080/19443994.2015.1132474.
[30] J. L. Gong, B. Wang, G. M. Zeng, C. P. Yang,
C. G. Niu, Q. Y. Niu, W. J. Zhou, Y. Liang, Removal of Cationic Dyes from Aqueous Solution using Magnetic Multi-Wall Carbon Nanotube Nanocomposite as Adsorbent, Journal of Hazardous Materials, Vol. 164, No. 2-3, 2009,
pp. 1517-1522, https://doi.org/10.1016/j.jhazmat.2008.09.072.
[31] H. Su, W. Li, Y. Han, N. Liu, Magnetic Carboxyl Unctional Nanoporous Polymer: Synthesis, Characterization and its application for Methylene Blue Adsorption, Scientific Reports, Vol. 8,
No. 6506, 2018, pp. 1-8, https://doi.org/10.1038/s41598-018-24873-3.
[32] A. Asfaram, M. Ghaedi, S. Hajati, A. Goudarzi,
A. A. Bazrafshan, Simultaneous Ultrasound-Assisted Ternary Adsorption of Dyes onto Copper-Doped Zinc Sulfide Nanoparticles Loaded on Activated Carbon: Optimization by Response Surface Methodology, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,
Vol. 145, No. 15, 2015, pp. 203-212, https://doi.org/10.1016/j.saa.2015.03.006.
[33] C. Chen, S. Mi, D. Lao, P. Shi, Z. Tong, Z. Li,
H. Hu, Single-step Synthesis of Eucalyptus Sawdust Magnetic Activated Carbon and its Adsorption Behavior for Methylene Blue, RSC Advances, Vol. 9, No. 39, 2019, pp. 22248-22262, https://doi.org/10.1039/C9RA03490K.
[34] L. T. Tran, H. V. Tran, T. D. Le, G. L. Bach,
L. D. Tran, Studying Ni(II) Adsorption of Magnetite/Graphene Oxide/Chitosan Nanocomposite, Advances in Polymer Technology, Vol. 2019. 2019, pp. 1-9, https://doi.org/10.1155/2019/8124351.
[35] K. Kadirvelu, Adsorption of Nickel(II) from Aqueous Solution onto Activated Carbon Prepared from Coirpith, Separation and Purification Technology, Vol. 24, No. 3, 2001, pp. 497-505, https://doi.org/10.1016/S1383-5866(01)00149-6.