Hoang Anh Le, Bui Duy Linh, Nguyen Thanh Tuan, Phan Quang Thang, Nguyen Viet Thanh, Pham Thu Huyen

Main Article Content

Abstract

Air pollution has become a pressing global concern due to its multifaceted impacts on the economy, society, and the environment. This study provides an in-depth investigation into the physicochemical pollution levels of Total Suspended Particulate (TSP) in inner-city and suburban areas of Hanoi, during both the dry and rainy seasons. TSP samples were collected using a high-volume air sampler. The morphology and particle size distribution of the TSP samples were analyzed using Field Emission Scanning Electron Microscopy, Scanning Electron Microscopy (SEM) combined with ImageJ software. The TSP samples were subsequently analyzed for major elements using the Particle Induced X-ray Emission (PIXE) method with a dedicated setup on a Pelletron 5SDH-2 accelerator system. The results show that TSP concentrations in the urban area (79.7 - 165.5 mg/m3) were higher than in the suburban area (52.2 - 162.2 mg/m3), and their concentrations in the dry season (60.8 - 165.5 μg/m³) were higher and exhibited greater fluctuation than in the rainy season (52.0 - 124.8 μg/m³). Coarse particles (PM10) constituted the majority (>85%) of the TSP. The concentrations of 17 major elements detected in the TSP samples via PIXE were arranged in the following order: Si > Ca > S > Al > Na > K > Cl > Fe > Mg > Zn > P > Ti > Mn > Pb > Cr > Cu > Ni.

Keywords: Physico-chemical properties, PIXE, TSP, Hanoi.

References

[1] R. D. Brook, J. R. Brook, S. Rajagopalan, Air Pollution: The Heart of the Problem, Current Hypertension Reports, Vol. 5, No. 1, 2003,
pp. 32-39,
https://doi.org/10.1007/s11906-003-0008-y.
[2] I. Manisalidis, E. Stavropoulou, A. Stavropoulos, E. Bezirtzoglou, Environmental and Health Impacts of Air Pollution: A Review, Frontiers in Public Health, Vol. 8, 2020, pp. 14, https://doi.org/10.3389/fpubh.2020.00014.
[3] T. T. Hien, D. H. Huy, P. A. Dominutti, N. D. T. Chi, J. R. Hopkins, M. Shaw, G. Forster, G. Mills, H. A. Le, D. Oram, Comprehensive Volatile Organic Compound Measurements and Their Implications for Groundlevel Ozone Formation in the Two Main Urban Areas of Vietnam, Atmospheric Environment, Vol. 269, 2022,
pp. 118872, https://doi.org/10.1016/j.atmosenv.2021.118872.
[4] E. Papp, D. Nagy, Z. Szoboszlai, A. Angyal,
Z. Török, Á. Csepregi, E. Furu, Z. Kertesz, Investigation of Aerosol Pollution Inside Trams in Debrecen, Hungary, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 477, 2020, pp. 138-143, https://doi.org/10.1016/j.nimb.2019.09.054.
[5] IQAir, 2024 World Air Quality Report, https://www.iqair.com/world-air-quality-report, 2025 (accessed on: August 5th, 2025).
[6] J. H. Li, T. T. T. Nguyen, K. G. Duong, Evaluation of Economic Development Process on Environmental Pollution Status in Hanoi, Vietnam, Applied Mechanics and Materials, Vol. 295, 2013, pp. 992-998, https://doi.org/10.4028/www.scientific.net/AMM.295-298.992.
[7] G. Hudson, H. Kaufmann, J. Nelson, M. Bonacci, Advances in the Use of PIXE and PESA for Air Pollution Sampling, Nuclear Instruments and Methods, Vol. 168, No. 1-3, 1980, pp. 259-263, https://doi.org/10.1016/0029-554X(80)91263-X.
[8] W. Maenhaut, N. Raes, W. Wang, Analysis of Atmospheric Aerosols By Particle-induced X-ray Emission, Instrumental Neutron Activation Analysis, and Ion Chromatography, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 269, No. 22, 2011, pp. 2693-2698, https://doi.org/10.1016/j.nimb.2011.08.012.
[9] N. H. Quyet, D. V. Thang, P. D. Khue, P. T. Nam, N. V. Khanh, N. T. Oanh, L. T. Hoa, C. D. Viet,
L. H. Khiem in Active Moss Biomonitoring Technique for Atmospheric Elemental Contamination in Hanoi Using Proton Induced
X-Ray Emission, Vietnam Conference on Nuclear Science and Technology VINANST-14, Agenda and Abstracts, 2021, pp. 9.
[10] R. Traversi, S. Becagli, G. Calzolai, M. Chiari,
M. Giannoni, F. Lucarelli, S. Nava, F. Rugi,
M. Severi, R. Udisti, A Comparison Between PIXE and ICP-AES Measurements of Metals in Aerosol Particulate Collected in Urban and Marine Sites in Italy, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 318, 2014, pp. 130-134, http://dx.doi.org/10.1016/j.nimb.2013.05.102.
[11] B. T. Hoa, N. T. Nghia, V. H. Phong, T. T. Anh, Evaluation of Thick Target PIXE Analysis in The 5SDH-2 Pelletron Accelerator Facility at VNU University of Science, VNU Journal of Science: Mathematics-Physics, Vol. 37, No. 4, 2021,
https//doi.org/10.25073/2588-1124/vnumap.4623.
[12] L. H. Khiem, N. T. Nghia, V. H. Phong, B. V. Loat, Proton Induced X-ray Emission (PIXE) Analysis on Thick Samples at HUS 5SDH-2 Tandem Accelerator System, Communications in Physics, Vol. 24, No. 3S2, 2014, pp. 1-7, https//doi.org/10.15625/0868-3166/24/3S2/5013.
[13] USEPA, IO Compendium Method IO-3.5: Compendium of Methods for the Determination of Inorganic Compounds in Ambient Air: Determination of Metals in Ambient Particulate Matter Using Inductively Coupled Plasma/Mass Spectrometry (ICP/MS), EPA/625/R-96/010a. Cincinnati, OH., 1999.
[14] B. D. Linh, H. A. Le, N. X. Truong, Physico-chemical Properties and Transboundary Transport of PM2.5 in Bien Hoa City, Dong Nai Province, Southeastern Vietnam, Environmental Science and Pollution Research, Vol. 30, No. 13, 2023,
pp. 36533-36544, https://doi.org/10.1007/s11356-022-24801-z.
[15] N. T. Thuan, N. D. Dat, N. M. Ngoc, N. T. T. Hoang, T. T. Hien, M. B. Chang, Atmospheric Polychlorinated Naphthalenes in a Tropical Megalopolis of Vietnam: Concentrations, Potential Sources, and Health Risk, Aerosol and Air Quality Research, Vol. 24, No. 8, 2024, pp. 240047, https://doi.org/10.4209/aaqr.240047.
[16] N. T. Tuan, L. H. Anh, B. D. Linh, N. D. Thang,
N. T. T. Ly, N.T. Thu, V. T. Hieu, Characterizing Aerosol Particulate Matter in Bien Hoa City, Dong Nai Province: Mass Concentration Levels, Ratios, and Long-Range Transport by HYSPLIT Model, Journal and Tropical Science and Engineering, Vol. 39, 2025, pp. 2-13, https://doi.org/10.58334/vrtc.jtst.n39.745.
[17] M. Inerb, W. Phairuang, P. Paluang, M. Hata,
M. Furuuchi, P. Wangpakapattanawong, Carbon and Trace Element Compositions of Total Suspended Particles (TSP) and Nanoparticles (PM0.1) in Ambient Air of Southern Thailand and Characterization of Their Sources, Atmosphere, Vol. 13, No. 4, 2022, pp. 626, https://doi.org/10.3390/atmos13040626.
[18] R. Jangirh, S. Ahlawat, R. Arya, A. Mondal,
L. Yadav, G. Kotnala, P. Yadav, N. Choudhary,
M. Rani, R. Banoo, Gridded Distribution of Total Suspended Particulate Matter (TSP) and Their Chemical Characterization Over Delhi During Winter, Environmental Science and Pollution Research, Vol. 29, 2022, pp. 17892-17918, https://doi.org/10.1007/s11356-021-16572-w.
[19] R. R. Leal, Elemental Morphological and Chemical Characterization of Individual TSP Particles by SEM-EDS, Microscopy and Microanalysis,
Vol. 26, No. S2, 2020, pp. 2202-2204, https://doi.org/10.1017/S1431927620020796.