Synthesis and characterization of carbon molecular sieve CMK-3
Main Article Content
Abstract
Abstract. A nanoporous carbon material was prepared using silica SBA-15 as a template and characterized by several techniques: XRD, N2-adsorption/desorption, SEM, and TEM. Carbonaceous material exhibits typical characteristics of nanostructed carbon family. The specific surface area and the mean pore size are about 1400 m2/g and 4 -12 nm, respectively.
Keywords: CMK-3, mesopores, carbon molecular sieve.References
[1] S. Jun, S.H. Joo, R. Ryoo, M. Kruk, M. Jaroniec, Z. Liu, T. Ohsuna, and O. Terasaki, Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure, J. Am. Chem. Soc. 122, (2000)10712.
[2] R. Ryoo, S.H. Joo, and S. Jun, Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation, J. Phys. Chem. B 103, (1999) 7743.
[3] T. Onfroy, F. Guenneau, M.-A. Springuel-Huet, A. Gedeon, First evidence of interconnected micro and mesopores in CMK-3 materials, Carbon 47 (2009) 2352.
[4] H. Huwe, M. Froba, Synthesis and characterization of transition metal and metal oxide nanoparticles inside mesoporous carbon CMK-3, Carbon 45 (2007) 304.
[5] Tamas I. Koranyi, Zdenk Vit, Janos B. Nagy, Support and pretreatment effects on the hydrotreating activity of SBA-15 and CMK-5 supported nickel phosphide catalysts, Catal.Today 130 (2008) 80.
[6] S. M. Holmes, P. Foran, E. P. L. Robertsa and J. M. Newton, Encapsulation of metal particles within the wall structure of mesoporous carbons, Chem. Commun. (2005) 1912.
[7] D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science 279 (1998) 548.
[8] S.H. Joo, S. Jun, R. Ryoo, Synthesis of ordered mesoporous carbon molecular sieves CMK-1, Micro. and Meso. Mater. 44-45 (2001) 153.
[9] W. Schmidt, Calculation of XRD patterns of simulated FDU-15, CMK-5, and CMK-3 carbon structures, Micro. and Meso. Mater. 117 (2009) 372.
[10] J. He, K. Ma, J. Jin, Z. Dong, J. Wang, R. Li, Preparation and characterization of octyl-modified ordered mesoporous carbon CMK-3 for phenol adsorption, Micro. and Meso. Mater. 121 (2009) 173.
[11] W.C. Choi, S.I. Woo, M.K Jeon, J.M. Sohn, M.R. Kim, and H.J. Jeon, Platinum nanoclusters studded in the microporous nanowalls of ordered mesoporous carbon, Adv. Mater. 17 (2005) 446.
A. Lu, A. Kiefer, W. Schmidt, and F. Schuth, Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures, Chem. Mater. 16 (2004) 100.
[2] R. Ryoo, S.H. Joo, and S. Jun, Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation, J. Phys. Chem. B 103, (1999) 7743.
[3] T. Onfroy, F. Guenneau, M.-A. Springuel-Huet, A. Gedeon, First evidence of interconnected micro and mesopores in CMK-3 materials, Carbon 47 (2009) 2352.
[4] H. Huwe, M. Froba, Synthesis and characterization of transition metal and metal oxide nanoparticles inside mesoporous carbon CMK-3, Carbon 45 (2007) 304.
[5] Tamas I. Koranyi, Zdenk Vit, Janos B. Nagy, Support and pretreatment effects on the hydrotreating activity of SBA-15 and CMK-5 supported nickel phosphide catalysts, Catal.Today 130 (2008) 80.
[6] S. M. Holmes, P. Foran, E. P. L. Robertsa and J. M. Newton, Encapsulation of metal particles within the wall structure of mesoporous carbons, Chem. Commun. (2005) 1912.
[7] D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores, Science 279 (1998) 548.
[8] S.H. Joo, S. Jun, R. Ryoo, Synthesis of ordered mesoporous carbon molecular sieves CMK-1, Micro. and Meso. Mater. 44-45 (2001) 153.
[9] W. Schmidt, Calculation of XRD patterns of simulated FDU-15, CMK-5, and CMK-3 carbon structures, Micro. and Meso. Mater. 117 (2009) 372.
[10] J. He, K. Ma, J. Jin, Z. Dong, J. Wang, R. Li, Preparation and characterization of octyl-modified ordered mesoporous carbon CMK-3 for phenol adsorption, Micro. and Meso. Mater. 121 (2009) 173.
[11] W.C. Choi, S.I. Woo, M.K Jeon, J.M. Sohn, M.R. Kim, and H.J. Jeon, Platinum nanoclusters studded in the microporous nanowalls of ordered mesoporous carbon, Adv. Mater. 17 (2005) 446.
A. Lu, A. Kiefer, W. Schmidt, and F. Schuth, Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures, Chem. Mater. 16 (2004) 100.