Luong Xuan Dien, Nguyen Xuan Truong, Ngo Duc Quan, Ken-ichi Yamashita, Kenichi Sugiura

Main Article Content

Abstract

Abstract: The 1(Ni) and Ni(II) complex was synthesized based on the reaction between
N,O-bidentate ligand 2-((methylimino)methyl) pyrene-1-ol (1) and nickel acetate in a mixed solvent of toluene, ethanol and NaOAc. The characters of the complex, such as elemental analysis (EA), IR, NMR, MS spectroscopy and single crystal X-ray diffraction, were investigated. With respect to the nickel atom, 1(Ni) complex adopts a distorted square planar trans-coordination geometry. Concerning the ligand arrangement, 1(Ni) complex has a step configuration with an angle of 35.5o between the mean planes of the pyrene rings in the two independent molecules and step distance S = 1.93 Å, whereas the referent nickel(II) bis(salicylaldiminato) takes a much smaller step configuration with an angle of 17.6o and step distance S = 0.845 Å (Chart 1). 


Keywords: Coordination chemistry, Nickel, Pyrene, expanded ligand, salicylaldimine.


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