Catalytic Conversion of Cellulose to 5-hydroxymethylfurfural (5-HMF) Over Nano SO42--ZrO2 /MCM-41 Catalysts
Main Article Content
Abstract
A zirconium catalyst system supported on MCM-41 (S-Z) with various weight components (4-20 wt.%) Was synthesized by the sol-gel method. Structure and Morphology Catalysts were characterized by X-RD, TEM, BET, FT-IR and TPD-NH3 methods. In this catalyst, ZrO2 is highly dispersed on the surface of MCM-41 capillaries. Catalytic activity and selectivity were evaluated by the effectiveness of mild hydrothermal decomposition of cellulose to 5-hydroxymethyl furfural (5-HMF). The results show that a catalyst with medium acidity exhibits a high selectivity of 5-HMF.
Keywords: S-Zr/MCM-41 materials, sol-gel methods, cellulose, 5-HMF.
Keywords: S-Zr/MCM-41 materials, sol-gel methods, cellulose, 5-HMF.
References
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[4] Yong-Xin Li, Li Y, Z.J. Qian, M.M. Kim, S.K. Kim, In vitro Antioxidant Activity of 5-HMF Isolated from Marine Red Alga Laurencia Undulata in Free-radical-mediated Oxidative Systems, J Microbiol Biotechnol 19(11) (2009) 1319-1327.
[5] J. Zaldivar, A. Martinez, L.O. Ingram, Effect of Selected Aldehydes on The Growth and Fermentation of Ethanologenic Escherichia coli, Biotechnology and Bioengineering 65(1) (1999) 24-33.
[6] Hongpeng Yan, Yu Yang, Dongmei Tong, Xi Xiang, Changwei Hu, Catalytic conversion of glucose to 5-hydroxymethylfurfural over SO42−/ZrO2 and SO42−/ZrO2–Al2O3 solid acid catalysts, Catalysis Communications 10(11) (2009) 1558-1563.
[7] J. Zhang, J. Li, L. Lin, Dehydration of sugar mixture to HMF and furfural over SO42-/ZrO2-TiO2 catalyst, BioRes. 9(3) (2014) 4194-4204.
[8] J.A. Rodrigues Jr, F.P. Cardoso, E.R. Lachter, L.R.M. Estevao, R.S.V. Nascimento, Correlating chemical structure and physical properties of vegetable oil esters, Journal of the American Oil Chemists' Society 83 (2006) 353.
[9] S. Karthikeyan, M.P. Pachamuthu, M.A. Isaacs, S. Kumar, A.F. Lee, G. Sekaran, Cu and Fe oxides dispersed on SBA-15: a Fenton type bimetallic catalyst for N,N-diethyl-p-phenyl diamine degradation, Appl. Catal. B-Environ. 199 (2016) 323-330.
[10] M.S.A. Salam, M.A. Betiha, S.A. Shaban, A.M. Elsabagh, R.M.A. El-Aal, F.Y. El Kady, Synthesis and characterization of MCM-41-supported nano zirconia catalysts, Egypt. J. Pet. 24 (2015) 49-57.
[11] A. Derylo-Marczewska, W. Gac, N. Popivnyak, G. Zukocinski, S. Pasieczna, The influence of preparation method on the structure and redox properties of mesoporous Mn-MCM-41 materials, Catal. Today 114 (2006) 293.
[12] L. Wang, A. Kong, B. Chen, H. Ding, Y. Shan, M. He, Direct synthesis, characterization of Cu-SBA-15 and its high catalytic activity in hydroxylation of phenol by H2O2, Catal. A Chem. 230 (2005) 143.
[13] A. Tuan Vu, H. Giang Le, T. T. Giang Pham, T.K. Hoa Tran, T. Phuong Dang, B. Manh Nguyen, D. Loi Vu, D. Gun Lee, Highly catalytic performance of novel Ni-Cu containing SBA-15 materials in the hydrodeoxygenation of guaiacol, Biointerface Res. Appl. Chem. 8 (3) (2018) 1-8.
[14] S. Wang, Y. Du, W. Zhang, W. et al., Catalytic conversion of cellulose into 5-hydroxymethylfurfural over chromium trichloride in ionic liquid, Korean J. Chem. Eng. 31 (2014) 1786. https://doi.org/10. 1007/s11814-014-0138-8.
[15] Xinhua Qi, Masaru Watanabe, Taku M. Aida, Richard L. SmithJr, Catalytical conversion of fructose and glucose into 5 hydroxymethylfurfural in hot compressed water by microwave heating, Catalysis Communications 9(13) (2008) 2244-2249.