Polyvinyl Butyral/Graphene Oxide Composite Coating for Properties Improvement
Main Article Content
Abstract
In this paper, polyvinyl butyral (PVB) composite coating was prepared with graphene oxide (GO) for improving mechanical properties, corrosion protection, thermal oxidation stability. Fourier-transform infrared spectroscopy (FT-IR), Thermogravimetric analysis (TGA), Field Emission Scanning Electron Microscopy (FESEM),... were used to examine the results. Presence of GO in composite coating was characterized by FT-IR. Corrosion protection of PVB coating containing GO was determined with salt mist testing with 4 cycles in 5% NaCl, each cycle included 2 hours spraying at 35±2 oC , kept in humidity condition for 7 days at 40± 2 oC with relative humidity of 93 ± 2%. Effects of GO on adhesion, flexibility, impact resistance, relative hardness and thermal oxidation stability of PVB composite coatings were also investigated. Results showed that GO content in PVB composite coating of 1.5 wt.% had significantly enhanced mechanical properties, corrosion resistance of PVB composite coating. Thermal oxidation resistance of PVB composite coating with 1.5 wt.% of GO was much higher than that of PVB composite coating without GO.
Keywords:
Polyvinyl butyral/Graphen oxide composite coating, physico-mechanical properties, anti-corrosion protection FT-IR, salt mist testing.
References
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[3] R. Brendgen, C. Grassmann, T. Grethe, B. Mahltig, A. S. Pfeiffer, Coatings with recycled polyvinyl butyral on polyester and polyamide mono- and multifilament yarns, J. Coat. Technol. Res. 18 (2021) 819-829.
http://doi.org/10.1007/s11998-020-00445-x
[4] K. Agnieszka, K. Krzysztof, Characterization of self-adhesive structural tapes modified with polyvinyl acetal resins. Int. J. Adhes. Adhes. 67 (2016) 44-48.
http://doi.org/10.1016/j.ijadhadh.2015.12.024
[5] A. F. Carreira, A. M. Pereira, E. P. Vaz, A. M. Cabral, T. Ghidini, L. Pigliaru, T. Rohr. Alternative corrosion protection pretreatments for aluminum alloys, J. Coat. Technol. Res. 14 (2017) 879–892.
http://doi.org/10.1007/s11998-017-9922-9
[6] H. Sugimoto, Y. Aoki, Preparation and physical properties of transparent foldable poly(methyl methacrylate) based materials using reactive poly(vinyl butyral), J. Polym. Res. 28 (2021) 121. http://doi.org/10.1007/s10965-021-02469-2
[7] O. Olabisi, K. Adewale, Handbook of Thermoplastics, CRC Press, New York, 2015.
[8] Y. Zuo, Z. Li, L. Chen, Y. Wang, Y. Gao, Treatment of the Rust Layer by Different Pyridine Derivatives and Its Effect on the Epoxy-Polyvinylbutyral Coating Directly Painted onto the Rust Mild Steel, Int. J. Electrochem. Sci. 12 (2017) 11728-11741,
http://doi.org/10.20964/2017.12.42
[9] P. Haghdadeh, M. Ghaffari, B. Ramezanzadeh, G. Bahlakeh, M. R. Saeb, The role of functionalized graphene oxide on the mechanical and anti-corrosion properties of polyurethane coating, J. Taiwan Inst. Chem. Eng. 86 (2018) 199-212.
https://doi.org/10.1016/j.jtice.2018.02.009
[10] G. Zhu, X. Cui, Y. Zhang, S. Chen, M. Dong, H. Liu, Q. Shaod, T. Ding, S. Wu, Z. Guo, Poly(vinyl butyral)/Graphene oxide/poly (methylhydrosiloxane) nanocomposite coating for improved aluminum alloy anticorrosion, Polymer 172 (2019) 415-422.
http://doi.org/10.1016/j.polymer.2019.03.056
[11] T. Niratiwongkorn, G. E. Luckachan, V. Mittal, Self-healing protective coatings of polyvinyl butyral/polypyrrole-carbon black composite on carbon steel, RSC Adv. 6 (2016) 43237–43249.
https://doi.org/10.1039/C6RA01619G
[12] T. Brantseva, S. Antonov, I. Y. Gorbunova, R. Korokhin, A. V. Shapagin, N. M. Smirnova, V. I. Solodilov, Epoxy modification with poly(vinyl acetate) and poly(vinyl butyral). I. Structure, thermal, and mechanical characteristics, J. Appl. Polym. Sci. 133 (2016) 44081.
http://doi.org/10.1002/app.44081
[13] N. T. Thanh, Improvement of Environmentally Friendly Alkyd Composite Coating with Graphene Oxide, MJCSM 7 (2022) 1-10.
https://doi.org/10.37934/mjcsm.7.1.110
[14] S. Das, P. Pandey, S. Mohanty, S. K. Nayak, Investigation into the Influence of UV Aging on Green Polyurethane/Nanosilica Composite Coatings Based on Transesterified Castor Oil and Palm Oil Isocyanate, J. Inorg. Organomet. Polym. Mater. 27 (2017) 641-657.
http://doi.org/10.1007/s10904-017-0506-z
[15] V. Pintus, S. Wei, M. Schreiner, Accelerated UV ageing studies of acrylic, alkyd, and polyvinyl acetate paints: Influence of inorganic pigments. Microchem. J. 124 (2016) 946-961.
https://doi.org/10.1016/j.microc.2015.07.009
[16] J. Si, J. Li, S. Wang, Y. Li, X. Jing, Enhanced thermal resistance of phenolic resin composites at low loading of graphene oxide, Compos.- A: Appl. Sci. Manuf. 54 (2013) 166-172.
http://doi.org/10.1016/j.compositesa.2013.07.019
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http://doi.org/10.1039/C8TA03651A
[18] G. Zhu, X. Cui, Y. Zhang, S. Chen, M. Dong, H. Liu, Q. Shao, T. Ding, S. Wu, Z. Guo, Poly (vinyl butyral)/Graphene oxide/poly (methylhydrosiloxane) nanocomposite coating for improved aluminum alloy anticorrosion, Polymer 172 (2019) 415-422.
https://doi.org/10.1016/j.polymer.2019.03.056
[19] A. Li, S. Chen, Z. Ma, M. Sun, G. Zhu, Y. Zhang, W. Wang, Corrosion protection properties of polyvinyl butyral/polyaniline-graphene oxide/poly (methylhydrosiloxane) composite coating for AA2024 aluminum alloy, Diam. Relat. Mater. 116(2021) 108397.
https://doi.org/10.1016/j.diamond.2021.108397
[20] M. Hajian, M. R. Reisi, G. A. Koohmareh, A. R. Z. Jam, Preparation and characterization of Polyvinylbutyral/Graphene Nanocomposite, J. Polym. Res. 19 (2012) 9966.
https://doi.org/10.1007/s10965-012-9966-6
[21] M. I Necolau, & A. M. Pandele, Recent Advances in Graphene Oxide-Based Anticorrosive Coatings: An Overview, Coatings, 10 (2020) 1149.
https://doi.org/10.3390/coatings10121149
[22] V. Pang, Z. J. Thompson, G. D. Joly, L. F. Francis, F. S. Bates, Block Copolymer and Nanosilica-Modified Epoxy Nanocomposites, ACS Appl. Polym. Mater. 3 (2021) 4156–4167.
https://doi.org/10.1021/acsapm.1c00619
[23] E. Moore, Fourier transform infrared spectroscopy (FTIR): methods, analysis, and research insights, Nova Science Publishers, Inc., New York, 2017.
[24] B. Yu, X. Wang, W. Xing, H. Yang, L. Song, Y. Hu, UV-Curable Functionalized Graphene Oxide/Polyurethane Acrylate Nanocomposite Coatings with Enhanced Thermal Stability and Mechanical Properties, Ind. Eng. Chem. Res. 51 (2012) 14629-14636.
https://doi.org/10.1021/ie3013852
[25] Z. Gao, C. Sun, L. Du, D. Yang, X. Zhang, Z. An, The Corrosion Resistance of Graphene-Modified Oily Epoxy Coating on AZ31 Magnesium Alloys, Front. Mater. 8 (2021) 739334.
https://doi.org/10.3389/fmats.2021.739334