Trung Do Dang

Main Article Content

Abstract

The intumescent retardant coating was fabricated by a combination of epoxy binder and flame-retardant ingredients for the steel plate. This paper investigates the influence of nanoclay content on improving fire properties of intumescent fire-retardant coatings. The fire performances of the coatings were determined by a fire test at 950oC for one hour. The coating degradation was characterized by Thermal gravimetric analysis (TGA). The morphology, composition of char was studied by Fourier transform infrared spectra (FTIR), scanning electron microscopy (SEM), and energy dispersive X-ray spectra (EDS). The results revealed that the intumescent coating containing 3 wt.% of nanoclay showed the best reduction in substrate temperature compared to the intumescent coating without nanoclay. The results also concluded that nanoclay increased fire protective performances of the intumescent coating.

Keywords: nanoclay, intumescent coating, epoxy, steel plate

References

[1] S. Duquesne, S. Magnet, C. Jama, R. Delobel, Intumescent paints: fire protective coatings for metallic substrates, Surf. Coat. Technol. 180-181 (2004) 302-307.
[2] R.G. Puri, A.S. Khanna, Intumescent coatings: A review on recent progress, J. Coat. Technol. Res. 14(1) (2017) 1-20.
[3] S. Ullah, F. Ahmad, A.M. Shariff, M.A. Bustam, Synergistic effects of kaolin clay on intumescent fire retardant coating composition for fire protection of structural steel substrate, Plym. Degrad. Stab. 110 (2014) 91-103.
[4] A. Gonzalez, A. Dasari, B. Herero, E. Plancher, J. Santaren, A. Esteban, S.H. Lim, Fire retardancy behavior of PLA based nanocomposites, Plym. Degrad. Stab. 97 (2012) 248-256.
[5] N.A. Isitman, C. Kaynak, Nanoclay and carbon nanotube as potential synergists of an organophosphorus flame-retardant in poly(methyl methacrylate), Plym. Degrad. Stab. 95 (2010) 1523-1532.
[6] M. Alexandre, P. Dubois, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials, Materials Science and Engineering: R: Reports 28 (2000) 1-63.
[7] Y.X. Lee, F. Ahmad, S. Kabir, P.J. Masset, E. Onate, G.H. Yeoh, Synergistic effects of halloysite clay and zirconium phosphate on thermal behavior of intumescent coating, J. Mater. Res. and Technol. 18 (2022) 4456-4469.
[8] J. Kaur, F. Ahmad, S. Ullah, P.S.M. Megat Yusoff, R. Ahmad, The role of bentonite clay on improvement in char adhesion of intumescent fire-retardant coating with steel substrate, Arab J. Sci. Eng. 42 (2017) 2043-2053.
[9] R.G. Puri, A.S. Khanna, Effect of cenospheres on the char formation and fire protective performance of water-based intumescent coatings on structural steel, Prog. Org. Coat. 92 (2016) 8-15.
[10] C.S. Chuang, H.J. Sheen, Effects of added nanoclay for styrene-acrylic resin on intumescent fire retardancy and CO/CO2 emission, J. Coat. Technol. Res. 17 (2019) 115-125.
[11] C.S. Chou, S.H. Lin, C.I. Wang, Preparation and characterization of the intumescent fire retardant coating with a new flame retardant, Adv. Powder Technol. 20 (2009) 169-176.
[12] M. Zia-ul-Mustafa, F. Ahmad, S. Ullah, N. Amir, Q.F. Gillani, Thermal and pyrolysis analysis of minerals reinforced intumescent fire retardant coating, Prog. Org. Coat. 102 (2017) 201-216.
[13] M.L. Bras, S. Bourbigot, B. Revel, Comprehensive study of the degradation of an intumescent EVA-based material during combustion, J. Matter. Sci. 34 (1999) 5777-5782.
[14] C. Feng, M. Liang, W. Chen, J. Huang, H. Liu, Flame retardancy and thermal degradation of intumescent flame retardant EVA composite with efficient charring agent, J. Anal. Appl. Pyrol. 113 (2015) 266-273.
[15] G. Camino, L. Costa, L. Trossarelli, F. Costanzi, A. Pagliari, Study of the mechanism of intumescent in fire retardant polymers: Part VI-Mechanism of ester formation in ammonium polyphosphate-pentaerythritol mixtures, Polym. Degrad. Stab. 12 (1985) 213-228.
[16] W. Zhan, L. Chen, F. Cui, Z. Gu, J. Jiang, Effects of carbon materials on fire protection and smoke suppression of waterborne intumescent coating, Prog. Org. Coat. 140 (2020) 105491-1055.