Electrochemical Properties of Fe2O3 Electrode in Alkaline Solution Containing K2S Additive

Bui Thi Hang

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Published Jul 18, 2018
DOI: https://doi.org/10.25073/2588-1124/vnumap.4274

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THI HANG, Bui. Electrochemical Properties of Fe2O3 Electrode in Alkaline Solution Containing K2S Additive. VNU Journal of Science: Mathematics - Physics, [S.l.], v. 34, n. 2, july 2018. ISSN 2588-1124. Available at: <https://js.vnu.edu.vn/MaP/article/view/4274>. Date accessed: 22 nov. 2024. doi: https://doi.org/10.25073/2588-1124/vnumap.4274.
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Issue
Vol 34 No 2
Section
Review Article

Main Article Content

Abstract

To find the suitable materials for Fe/air battery anode, in this study Fe2O3 electrodes were prepared using Fe2O3 nanoparticles. The size and morphology of Fe2O3 material were observed by scanning electron microscope (SEM). The electrochemical properties of the Fe2O3 electrode in alkaline solution were investigated by using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The effects of K2S additive in electrolyte solution on the electrochemical characteristics of Fe2O3 electrodes were also investigated. The obtained results show that the additive strongly affected on the impedance, redox reaction rate and cyclability of Fe2O3 electrode


Keywords: Fe2O3 nanoparticles, Fe2O3 electrode, K2S additive, Fe-air battery.


References


[1] A. K. Manohar, S. Malkhandi, B.Yang, C. Yang, G.K.S. Prakash, and S.R. Narayanan, A High Performance Rechargeable Iron Electrode for Large Scale Battery Based Energy Storage, Journal of The Electrochemical Society 159 (2012) A1209.
[2] A. Inoishi, Y. W. Ju, S. Ida, T. Ishihara, Fe-air rechargeable battery using oxide ion conducting electrolyte of Y2O3 stabilized ZrO2, Journal of Power Sources 229 (2013) 12.
[3] C. Kao, K. Chou, Iron/carbon-black composite nanoparticles as an iron electrode material in a paste type rechargeable alkaline battery, Journal of Power Sources 195 (2010) 2399.
[4] B. Cui, H. Xin, S. Liu, X. Liu, Y. Hao, Q. Guo, and S. Licht, Improved Cycle Iron Molten Air Battery Performance Using a Robust Fin Air Electrode, Journal of The Electrochemical Society 164 (2017) A88.
[5] A. Paulraj, Y. Kiros, B. Skarman, and H. Vidarsson, Core/Shell Structure Nano-Iron/Iron Carbide Electrodes for Rechargeable Alkaline Iron Batteries, Journal of The Electrochemical Society 164 (2017) A1665.
[6] U. S. Department of Energy, APRA-Efunding announcement, GridscaleRampable Intermittently Dispatchable Storage, 2010.
[7] S. Narayanan, G. S. Prakash, A. Manohar, B. Yang, S. Malkhandi, A. Kindler, Materials Challenges and Technical Approaches for Realizing Inexpensive and Robust Iron-Air Batteries for Large-Scale Energy Storage,Solid State Ionics 216 (2012) 105.
[8] T.S. Balasubramanian, A.K. Shukla, Effect of metal-sulfide additives on charge/discharge reactions of the alkaline iron electrode, J. Power Sources 41 (1993) 99.
[9] J. Cerny, J. Jindra, K. Micka, Comparative study of porous iron electrodes, J. Power Sources 45 (1993) 267.
[10] P. Periasamy, B.R. Babu, S.V. Iyer, Performance Characterization of Sintered Iron Electrodes in Nickel/Iron Alkaline Batteries, J. Power Sources 62 (1996) 9.
[11] C.A. Caldas, M.C. Lopes, I.A. Carlos, The role of FeS and (NH4)2CO3 additives on the pressed type Fe electrode, J. Power Sources 74 (1998) 108.
[12] C.A.C. Souza, I.A. Carlos, M.C. Lopes, G.A. Finazzi, M.R.H. de Almeida, Short communication Self-discharge of Fe–Ni alkaline batteries, J. Power Sources 132 (2004) 288.
[13] A. Manohar, C.Yang, S. Malkhandi, G.K.S. Prakash, and S.R.Narayanan, Enhancing the Performance of the Rechargeable Iron Electrode in Alkaline Batteries with Bismuth Oxide and Iron Sulfide Additives”, Journal of The Electrochemical Society 160 (2013) A2078.
[14] J. Cerny, K. Micka, Voltammetric study of an iron electrode in alkaline electrolytes, J. Power Sources 25 (1989) 111.
[15] P. Periasamy, B.R. Babu, S.V. Iyer, Electrochemical behaviour of Teflon-bonded iron oxide electrodes in alkaline solutions, J. Power Sources 63 (1996) 79.
[16] B. T. Hang, T. Watanabe, M. Egashira, I. Watanabe, S. Okada, J. Yamaki, The effect of additives on the electrochemical properties of Fe/C composite for Fe/air battery anode, J. Power Sources 155 (2006) 461.
[17] A. K. Manohar, C. Yang, and S.R. Narayanan, The Role of Sulfide Additives in Achieving Long Cycle Life Rechargeable Iron Electrodes in Alkaline Batteries, Journal of The Electrochemical Society, 162 (2015) A1864.
[18] K. Micka, Z. Zabransky, Study of iron oxide electrodes in an alkaline electrolyte, J. Power Sources 19 (1987) 315.
[19] M. Jayalakshmi, B.N. Begumi, V.R. Chidambaram, R. Sabapathi, V.S. Muralidharan, Role of activation on the performance of the iron negative electrode in nickel/iron cells, J. Power Sources 39 (1992) 113.
[20] B.T. Hang, M. Egashira, I. Watanabe, S. Okada, J. Yamaki, S. Yoon, I. Mochida, The effect of carbon species on the properties of Fe/C composite for metal-air battery anode, J. Power Sources 143 (2005) 256.
[21] B. T. Hang, T. Watanabe, M.Egashira, I. Watanabe,S. Okada, J.Yamaki, The Effect of Additives on the Electrochemical Properties of Fe/C Composite for Fe/Air Battery Anode, J. Power Sources 155 (2006) 461.
[22] D. W. Shoesmith, P. Taylor, M. G. Bailey and B. Ikeda,Electrochemical behaviour of iron in alkaline solutions,Electrochim. Acta, 23 (1978), 903.
[23] G. P. Kalaignan, V. S. Muralidharan and K. I. Vasu, Triangular potential sweepvoltammetricstudy of porous iron electrodes in alkali solutions,J. Appl. Electrochem., 17 (1987), 1083.

References

[1] A. K. Manohar, S. Malkhandi, B.Yang, C. Yang, G.K.S. Prakash, and S.R. Narayanan, A High Performance Rechargeable Iron Electrode for Large Scale Battery Based Energy Storage, Journal of The Electrochemical Society 159 (2012) A1209.
[2] A. Inoishi, Y. W. Ju, S. Ida, T. Ishihara, Fe-air rechargeable battery using oxide ion conducting electrolyte of Y2O3 stabilized ZrO2, Journal of Power Sources 229 (2013) 12.
[3] C. Kao, K. Chou, Iron/carbon-black composite nanoparticles as an iron electrode material in a paste type rechargeable alkaline battery, Journal of Power Sources 195 (2010) 2399.
[4] B. Cui, H. Xin, S. Liu, X. Liu, Y. Hao, Q. Guo, and S. Licht, Improved Cycle Iron Molten Air Battery Performance Using a Robust Fin Air Electrode, Journal of The Electrochemical Society 164 (2017) A88.
[5] A. Paulraj, Y. Kiros, B. Skarman, and H. Vidarsson, Core/Shell Structure Nano-Iron/Iron Carbide Electrodes for Rechargeable Alkaline Iron Batteries, Journal of The Electrochemical Society 164 (2017) A1665.
[6] U. S. Department of Energy, APRA-Efunding announcement, GridscaleRampable Intermittently Dispatchable Storage, 2010.
[7] S. Narayanan, G. S. Prakash, A. Manohar, B. Yang, S. Malkhandi, A. Kindler, Materials Challenges and Technical Approaches for Realizing Inexpensive and Robust Iron-Air Batteries for Large-Scale Energy Storage,Solid State Ionics 216 (2012) 105.
[8] T.S. Balasubramanian, A.K. Shukla, Effect of metal-sulfide additives on charge/discharge reactions of the alkaline iron electrode, J. Power Sources 41 (1993) 99.
[9] J. Cerny, J. Jindra, K. Micka, Comparative study of porous iron electrodes, J. Power Sources 45 (1993) 267.
[10] P. Periasamy, B.R. Babu, S.V. Iyer, Performance Characterization of Sintered Iron Electrodes in Nickel/Iron Alkaline Batteries, J. Power Sources 62 (1996) 9.
[11] C.A. Caldas, M.C. Lopes, I.A. Carlos, The role of FeS and (NH4)2CO3 additives on the pressed type Fe electrode, J. Power Sources 74 (1998) 108.
[12] C.A.C. Souza, I.A. Carlos, M.C. Lopes, G.A. Finazzi, M.R.H. de Almeida, Short communication Self-discharge of Fe–Ni alkaline batteries, J. Power Sources 132 (2004) 288.
[13] A. Manohar, C.Yang, S. Malkhandi, G.K.S. Prakash, and S.R.Narayanan, Enhancing the Performance of the Rechargeable Iron Electrode in Alkaline Batteries with Bismuth Oxide and Iron Sulfide Additives”, Journal of The Electrochemical Society 160 (2013) A2078.
[14] J. Cerny, K. Micka, Voltammetric study of an iron electrode in alkaline electrolytes, J. Power Sources 25 (1989) 111.
[15] P. Periasamy, B.R. Babu, S.V. Iyer, Electrochemical behaviour of Teflon-bonded iron oxide electrodes in alkaline solutions, J. Power Sources 63 (1996) 79.
[16] B. T. Hang, T. Watanabe, M. Egashira, I. Watanabe, S. Okada, J. Yamaki, The effect of additives on the electrochemical properties of Fe/C composite for Fe/air battery anode, J. Power Sources 155 (2006) 461.
[17] A. K. Manohar, C. Yang, and S.R. Narayanan, The Role of Sulfide Additives in Achieving Long Cycle Life Rechargeable Iron Electrodes in Alkaline Batteries, Journal of The Electrochemical Society, 162 (2015) A1864.
[18] K. Micka, Z. Zabransky, Study of iron oxide electrodes in an alkaline electrolyte, J. Power Sources 19 (1987) 315.
[19] M. Jayalakshmi, B.N. Begumi, V.R. Chidambaram, R. Sabapathi, V.S. Muralidharan, Role of activation on the performance of the iron negative electrode in nickel/iron cells, J. Power Sources 39 (1992) 113.
[20] B.T. Hang, M. Egashira, I. Watanabe, S. Okada, J. Yamaki, S. Yoon, I. Mochida, The effect of carbon species on the properties of Fe/C composite for metal-air battery anode, J. Power Sources 143 (2005) 256.
[21] B. T. Hang, T. Watanabe, M.Egashira, I. Watanabe,S. Okada, J.Yamaki, The Effect of Additives on the Electrochemical Properties of Fe/C Composite for Fe/Air Battery Anode, J. Power Sources 155 (2006) 461.
[22] D. W. Shoesmith, P. Taylor, M. G. Bailey and B. Ikeda,Electrochemical behaviour of iron in alkaline solutions,Electrochim. Acta, 23 (1978), 903.
[23] G. P. Kalaignan, V. S. Muralidharan and K. I. Vasu, Triangular potential sweepvoltammetricstudy of porous iron electrodes in alkali solutions,J. Appl. Electrochem., 17 (1987), 1083.