Vu Hoang Huong

Main Article Content

Abstract

The Sn3O4/g-C3N4 composites were produced by an annealing mixture of g-C3N4 and Sn3O4, which were prepared by calcining urea and hydrothermally treating of SnCl2 solution, respectively. Chacterization of the samples was investigated by powder X-ray diffraction (XRD), Scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), Photoluminescence (PL) and UV-Vis spectra. Studying the degradation of Rhodamine B (RhB) in the presence of visible light showed that the combination of Sn3O4 and g-C3N4 has an enhanced ability in the photocatalysis in comparison with the individual components. From kinetic investigations of RhB degradation, it is found that the SCN25 catalyst has the highest rate constant of 18.14 (min-1 x 103), which was about 11.4 times larger than that of pure g-C3N4. It is possible to explain the improved photocatalytic activity of Sn3O4/g-C3N4 composites by using the
Z-scheme pathway.


 


 


 

Keywords: Visible light, Rhodamine B, Composite, Z-scheme.

References

[1] J. Singh, P. Kumari, S. Basu, Degradation of Toxic Industrial Dyes Using SnO2/g- C3N4 Nanocomposites: Role of Mass Ratio on Photocatalytic Activity, Journal of Photochemistry and Photobiology A: Chemistry, Vol. 371 , 2019, pp. 136-143, https://doi.org/10.1016/j.jphotochem.2018.11.014.
[2] J. Liang, X. Yang, Y. Wang, P. He, H. Fu, Y. Zhao, Q. Zou, X. An, A Review on g-C3N4 Incorporated with Organics for Enhanced Photocatalytic Water Splitting, Journal of Materials Chemistry A, Vol. 9, No. 22, 2021,
pp. 12898-12922, https://doi.org/10.1039/D1TA00890K.
[3] Z. Tong, D. Yang, T. Xiao, Y. Tian, Z. Jiang, Biomimetic Fabrication of g-C3N4/TiO2 Nanosheets with Enhanced Photocatalytic Activity Toward Organic Pollutant Degradation, Chemical Engineering Journal, Vol. 260, 2015,
pp 117-125, https://doi.org/10.1016/j.cej.2014.08.072.
[4] C. Li, S. Yu, H. Dong, C. Liu, H. Wu, H. Che, G. Chen, Z-scheme Mesoporous Photocatalyst Constructed by Modification of Sn3O4 Nanoclusters on g-C3N4 Nanosheets with Improved Photocatalytic Performance and Mechanism Insight, Applied Catalysis B: Environmental, Vol. 238, 2018, pp. 284-293, https://doi.org/10.1016/j.apcatb.2018.07.049.
[5] Y. He, D. Li, J. Chen, Y. Shao, J. Xian, X. Zheng, P. Wang, Sn3O4: A Novel Heterovalent-Tin Photocatalyst with Hierarchical 3D Nanostructures Under Visible Light, RSC Advances, Vol. 4, 2014, pp. 1266-1269, https://doi.org/10.1039/C3RA45743E.
[6] Y. S. Liu, A. Yamaguchi, Y. Yang, H. Abe, S. Ueda, T. Tanabe, M. Miyauchi, Visible-Light-Induced CO2 Reduction by Mixed-Valence Tin Oxide, ACS Applied Energy Materials, Vol. 4, 2021, pp. 13415-13419, https://doi.org/10.1021/acsaem.1c02896.
[7] W. Lei, F. Wang, X. Pan, Z. Ye, B. Lu, Z-scheme MoO3-2D SnS Nanosheets Heterojunction Assisted g-C3N4 Composite for Enhanced Photocatalytic Hydrogen Evolutions, International Journal of Hydrogen Energy, Vol. 47, 2022, pp. 10877-10890, https://doi.org/10.1016/j.ijhydene.2022.01.139.
[8] L. Yang, J. Huang, L. Shi, L. Cao, H. Liu, Y. Liu, Y. Li, H. Song, Y. Jie, J. Ye, Sb Doped SnO2-Decorated Porous g-C3N4 Nanosheet Heterostructures with Enhanced Photocatalytic Activities Under Visible Light Irradiation, Applied Catalysis B: Environmental, Vol. 221, 2018, pp. 670-680, https://doi.org/10.1016/j.apcatb.2017.09.041.
[9] H. Wu, S. Yu, Y. Wang, J. Han, L. Wang, N. Song, H. Dong, C. Li, A Facile One-Step Strategy to Construct 0D/2D SnO2/g-C3N4 Heterojunction Photocatalyst for High-Efficiency Hydrogen Production Performance from Water Splitting, International Journal of Hydrogen Energy, Vol. 45, 2020, pp. 30142-30152, https://doi.org/10.1016/j.ijhydene.2020.08.112.
[10] M. Ismael, E. Elhaddad, M. Wark, Construction of SnO2/g-C3N4 Composite Photocatalyst with Enhanced Interfacial Charge Separation and High Efficiency for Hydrogen Production and Rhodamine B Degradation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 638, 2022, pp. 128-288, https://doi.org/10.1016/j.colsurfa.2022.128288.
[11] D. P. Bui, T. D. Nguyen, T. T. L. Vo, T. M. Cao, S. J. You, V. V. Pham, SnO2–x Nanoparticles Decorated on Graphitic Carbon Nitride as S-Scheme Photocatalysts for Activation of Peroxymonosulfate, ACS Applied Nano Materials, Vol. 4, 2021, pp. 9333-9343, https://doi.org/10.1021/acsanm.1c01801.